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Finite element method-simulated Li + flux distributions in solid-state batteries with (a) a pristine LiFePO 4 cathode, (b) a composite LiFePO 4 cathode with micro-LLZTO particles, and (c) a composite LiFePO 4 cathode with nano-LLZTO particles after 400 s of discharge. Two composite cathodes have the same volume of added LLZTO particles. Magnified views are shown on the right. Simulated Li + flux over time in (d) the entire cathode region and (e) the <t>cathode–electrolyte</t> interface. Discharge rate: 0.2C.
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Finite element method-simulated Li + flux distributions in solid-state batteries with (a) a pristine LiFePO 4 cathode, (b) a composite LiFePO 4 cathode with micro-LLZTO particles, and (c) a composite LiFePO 4 cathode with nano-LLZTO particles after 400 s of discharge. Two composite cathodes have the same volume of added LLZTO particles. Magnified views are shown on the right. Simulated Li + flux over time in (d) the entire cathode region and (e) the <t>cathode–electrolyte</t> interface. Discharge rate: 0.2C.
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Finite element method-simulated Li + flux distributions in solid-state batteries with (a) a pristine LiFePO 4 cathode, (b) a composite LiFePO 4 cathode with micro-LLZTO particles, and (c) a composite LiFePO 4 cathode with nano-LLZTO particles after 400 s of discharge. Two composite cathodes have the same volume of added LLZTO particles. Magnified views are shown on the right. Simulated Li + flux over time in (d) the entire cathode region and (e) the <t>cathode–electrolyte</t> interface. Discharge rate: 0.2C.
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Finite element method-simulated Li + flux distributions in solid-state batteries with (a) a pristine LiFePO 4 cathode, (b) a composite LiFePO 4 cathode with micro-LLZTO particles, and (c) a composite LiFePO 4 cathode with nano-LLZTO particles after 400 s of discharge. Two composite cathodes have the same volume of added LLZTO particles. Magnified views are shown on the right. Simulated Li + flux over time in (d) the entire cathode region and (e) the <t>cathode–electrolyte</t> interface. Discharge rate: 0.2C.
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Finite element method-simulated Li + flux distributions in solid-state batteries with (a) a pristine LiFePO 4 cathode, (b) a composite LiFePO 4 cathode with micro-LLZTO particles, and (c) a composite LiFePO 4 cathode with nano-LLZTO particles after 400 s of discharge. Two composite cathodes have the same volume of added LLZTO particles. Magnified views are shown on the right. Simulated Li + flux over time in (d) the entire cathode region and (e) the <t>cathode–electrolyte</t> interface. Discharge rate: 0.2C.
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peo/liclo4 composite solid electrolyte  (Verlag GmbH)
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Finite element method-simulated Li + flux distributions in solid-state batteries with (a) a pristine LiFePO 4 cathode, (b) a composite LiFePO 4 cathode with micro-LLZTO particles, and (c) a composite LiFePO 4 cathode with nano-LLZTO particles after 400 s of discharge. Two composite cathodes have the same volume of added LLZTO particles. Magnified views are shown on the right. Simulated Li + flux over time in (d) the entire cathode region and (e) the <t>cathode–electrolyte</t> interface. Discharge rate: 0.2C.
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Finite element method-simulated Li + flux distributions in solid-state batteries with (a) a pristine LiFePO 4 cathode, (b) a composite LiFePO 4 cathode with micro-LLZTO particles, and (c) a composite LiFePO 4 cathode with nano-LLZTO particles after 400 s of discharge. Two composite cathodes have the same volume of added LLZTO particles. Magnified views are shown on the right. Simulated Li + flux over time in (d) the entire cathode region and (e) the <t>cathode–electrolyte</t> interface. Discharge rate: 0.2C.
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Finite element method-simulated Li + flux distributions in solid-state batteries with (a) a pristine LiFePO 4 cathode, (b) a composite LiFePO 4 cathode with micro-LLZTO particles, and (c) a composite LiFePO 4 cathode with nano-LLZTO particles after 400 s of discharge. Two composite cathodes have the same volume of added LLZTO particles. Magnified views are shown on the right. Simulated Li + flux over time in (d) the entire cathode region and (e) the cathode–electrolyte interface. Discharge rate: 0.2C.

Journal: ACS Applied Materials & Interfaces

Article Title: LiFePO 4 /Nano-LLZTO Composite Cathodes for Enhanced Performance of Solid-State Lithium Batteries

doi: 10.1021/acsami.5c25967

Figure Lengend Snippet: Finite element method-simulated Li + flux distributions in solid-state batteries with (a) a pristine LiFePO 4 cathode, (b) a composite LiFePO 4 cathode with micro-LLZTO particles, and (c) a composite LiFePO 4 cathode with nano-LLZTO particles after 400 s of discharge. Two composite cathodes have the same volume of added LLZTO particles. Magnified views are shown on the right. Simulated Li + flux over time in (d) the entire cathode region and (e) the cathode–electrolyte interface. Discharge rate: 0.2C.

Article Snippet: The microstructures and elemental compositions of the LLZTO, composite cathodes and composite solid electrolyte were characterized using a SEM (SU8010, Hitachi, Japan) equipped with an energy-dispersive X-ray spectroscopy (EDS) system.

Techniques:

(a) Cycling performance of SSLBs with pristine LiFePO 4 and LiFePO 4 /nano-LLZTO composite cathodes at 0.2C. (b, d) Corresponding galvanostatic charge–discharge profiles for SSLBs using (b) pristine LiFePO 4 and (e) LiFePO 4 /nano-LLZTO cathodes. (c, e) Schematic illustrations of the proposed mechanisms for enhanced conductivity (c) within the composite cathode and (e) at the interface between the cathode and the composite solid electrolyte (CSE).

Journal: ACS Applied Materials & Interfaces

Article Title: LiFePO 4 /Nano-LLZTO Composite Cathodes for Enhanced Performance of Solid-State Lithium Batteries

doi: 10.1021/acsami.5c25967

Figure Lengend Snippet: (a) Cycling performance of SSLBs with pristine LiFePO 4 and LiFePO 4 /nano-LLZTO composite cathodes at 0.2C. (b, d) Corresponding galvanostatic charge–discharge profiles for SSLBs using (b) pristine LiFePO 4 and (e) LiFePO 4 /nano-LLZTO cathodes. (c, e) Schematic illustrations of the proposed mechanisms for enhanced conductivity (c) within the composite cathode and (e) at the interface between the cathode and the composite solid electrolyte (CSE).

Article Snippet: The microstructures and elemental compositions of the LLZTO, composite cathodes and composite solid electrolyte were characterized using a SEM (SU8010, Hitachi, Japan) equipped with an energy-dispersive X-ray spectroscopy (EDS) system.

Techniques: